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Chemical Process Industry News
News Release from: Elga Process Water | Subject: BP Hull water treatment
Edited by the Processingtalk Editorial
Team on 11 January 2008
Elga maintains BP water plant
reliability
Elga Process Water was on hand to provide engineering repairs when the ion exchange plant feeding steam generators for the BP Hull site acetic acid plant showed signs of failure
The BP site at Hull is Europe's largest manufacturing facility for acetic acid Its integrity was threatened when its water treatment plant, M186, began to corrode: which threatened the availability of the continuous supply of water to the site steam generators
This article was originally published on Processingtalk on 17 Dec 2002 at 8.00am (UK)
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Fortunately Elga Process Water engineers were able to design and install replacement internals for the plant without compromising production.
Acetic acid is one of the world's most important chemicals, and is a key raw material for the production of a wide number of products we simply couldn't do without in our everyday lives, including washing powder, drink bottles and food packaging.
Other chemicals from the BP site are equally important: acetic anhydride is used in the synthesis of a number of pharmaceuticals such as aspirin and paracetamol, ethyl acetate is a solvent for high-resolution printing inks and laminating adhesives, and vinyl acetate monomer (VAM) is used in the paint on our walls, the adhesive in our furniture, in the manufacture of our clothes, the soles of our shoes and in the paper this is printed on (except we're on your screen - Ed - and by the way, following Sir Winston, we would prefer "...on which this is printed").
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The water treatment plant, which consists of three 140m3/h streams each with weak and strong acid cation exchangers, a common degasser and weak and strong base anion exchangers, was installed in 1997 to provide feed water to the factory 64barg and 45barg steam boilers.
Without steam, production stops - therefore the reliability of the water treatment plant is critical to the site.
The problem occurred in the 2.4m diameter strong acid cation exchangers.
The units are co-counter current flow regenerated using a technique in which 25% of the sulphuric acid regenerant flows simultaneously downwards through the top part of the resin bed with the remaining 75% flowing upwards through the bottom section, to be collected in a central header and lateral system.
The forces on this collector system during the occasional backwash and possibly during regeneration can be very high and, if it is not properly designed and supported, it can move, leading to eventual mechanical failure.
Within a few years of installation the units were suffering from loss of resin and inefficient regeneration.
BP stated "The strong acid cation exchange units were backwashed on an infrequent basis, however the collector systems were not adequately supported and there was enough movement to damage the protective rubber coating.
This allowed the regenerant acid to attack the carbon steel underneath resulting in corrosion and failure of the collector header to vessel manifold joint with a resultant escape of resin, ineffective regeneration, eventually leading to total failure of the units".
BP Works Engineering planned to retrofit new collectors.
They were able to design and install the necessary supports inside the pressure vessels and fitted new stainless steel nozzles on the SAC shell for connection to the collector system.
The design of the collector system itself was a job for specialists, so BP selected Elga Process Water, whose experience in the engineering design of ion exchange units goes back over eighty years.
Elga Process Water designed and fabricated a complete new stainless steel header with laterals fabricated from stainless steel wedge wire.
The modifications were carried out in three stages over a period of four months.
BP stated: "The modified internals have performed well, with good distribution of the regenerant acid, greatly improved reliability, and with no further problems".
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